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Archive for the ‘Gold’ Category

Gold catalyzed [2+2]

Posted by naturalproductman on March 20, 2013

Antonio Echavarren and co-workers from ICIQ in Spain have reported in Org Lett on a gold catalyzed intramolecular [2+2] between an alkene and alkyne.

[2+2]

OL paper

Posted in Methodology, Transition Metal, Cycloaddition, Gold, Pericyclic reactions, [2+2] | Leave a Comment »

Alkynoates and allylic ethers

Posted by naturalproductman on February 27, 2013

Young Ho Rhee and co-workers from Pohang University of Science and Technology have reported in Org Lett on a gold catalyzed coupling of an alkynoate and allylic ether.

ether

OL paper

Posted in Methodology, Mechanistic, Transition Metal, Cascade Reactions, Sigmatropic Rearrangements, Gold | Leave a Comment »

Imino-Nazarov reaction

Posted by naturalproductman on November 8, 2012

Richard Hsung and co-workers published in Org Lett on an imino Nazarov reaction catalyzed by gold and silver.

imino Nazarov

OL paper

Posted in Methodology, Transition Metal, Cascade Reactions, Named Reactions, Gold, Nazarov cyclization | Leave a Comment »

[2+2] by cationic gold

Posted by naturalproductman on October 17, 2012

Jose Gonzalez and co-workers from the University of Oviedo have reported in ACIE on a cationic gold catalyzed [2+2] reaction.

2+2

ACIE paper

Posted in Methodology, Transition Metal, Gold, [2+2] | Leave a Comment »

Oxazole synthesis intermolecularly

Posted by naturalproductman on October 11, 2012

Liming Zhang and co-workers at UCSB have reported in JACS on an approach to access oxazoles through an intermolecular coupling between an amide and an alkyne.  This method uses gold and is good because many ways to make oxazoles intramolecularly are known but not intermolecularly.

intermolecular

JACS paper

Posted in Methodology, Transition Metal, Cascade Reactions, Gold | Leave a Comment »

Biaryl synthesis

Posted by naturalproductman on October 4, 2012

Christopher Russell and colleagues at the University of Bristol have reported in Science on a gold catalyzed C-H activation approach for biaryl synthesis.

Science paper

Posted in Methodology, Transition Metal, C-H activation, Gold | Leave a Comment »

Quinocarcin synthesis

Posted by naturalproductman on August 13, 2012

Hiroaki Ohno and co-workers from Kyoto University have reported in ACIE on the synthesis of quinocarcin.

alkaloid

ACIE paper

Posted in Alkaloids, Cascade Reactions, Gold, Methodology, Total Synthesis, Transition Metal | Leave a Comment »

Gold cascade cyclization

Posted by naturalproductman on January 7, 2012

Antonio Echavarran and co-worker at ICIQ in Spain have reported in Synlett on a gold catalyzed cyclization of an enynone.
gold

Synlett paper

Posted in Cascade Reactions, Gold, Methodology, Transition Metal | Leave a Comment »

Allyl transfer with gold

Posted by naturalproductman on December 21, 2011

Daesung Lee and co-workers at the University of Illinois in Chicago have reported in Organic Letters on a gold catalyzed formation of cyclopentenes from enynes.

gold

OL paper

Posted in Cascade Reactions, Gold, Mechanistic, Methodology, Transition Metal | Leave a Comment »

Enyne cross metathesis

Posted by naturalproductman on December 14, 2011

Seunghoon Shin and co-workers at Hanyang University have reported in JACS on a gold catalyzed enyne cross metathesis between propiolic acids and alkenes.

gold

JACS paper

Posted in Cascade Reactions, Computational, DFT, Gold, Mechanistic, Metathesis, Methodology, Transition Metal | Leave a Comment »

 
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