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Archive for the ‘Palladium’ Category

Kendomycin synthesis

Posted by naturalproductman on March 14, 2014

Hirokazu Arimoto and co-workers from Tohoku University have reported in ACIE on the synthesis of kendomycin.

kendomycin

ACIE paper

Posted in Methodology, Named Reactions, Palladium, Total Synthesis, Transition Metal, Tsuji-Trost | Leave a Comment »

C-H activation methodology

Posted by naturalproductman on March 13, 2014

How crazy is it that one research group publishes in Nature and Science in the SAME week?

 

Science paper

 

Nature paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | Leave a Comment »

Silyl Heck reaction

Posted by naturalproductman on August 30, 2013

Donald Watson and colleague have reported in JACS on silyl Heck variant.

vinyl silyl ethers

JACS paper

Posted in cross coupling, Heck, Methodology, Palladium, Transition Metal | Leave a Comment »

C-P bond from a C-H bond

Posted by naturalproductman on July 24, 2013

Masahiro Murakami and co-workers have reported in ACIE on a C-P bond formation.

C-H

ACIE paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | Leave a Comment »

C-H activation

Posted by naturalproductman on July 24, 2013

Nobuharu Iwasawa and co-workers at Tokyo Institute of Technology have reported in JACS on a palladium catalyzed CO2 fixation reaction to form coumarins from a vinyl phenol.

coumarin

JACS paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | Leave a Comment »

Formyl source

Posted by naturalproductman on July 11, 2013

Kei Manabe and co-workers at the University of Shizuoka have reported in ACIE on the use of N-formylsaccharin as a formyl source.

formyl

ACIE paper

Posted in Cascade Reactions, Methodology, Palladium, Transition Metal | Leave a Comment »

Anti-Markovnikov oxidation of allylic esters

Posted by naturalproductman on April 18, 2013

Ben Feringa and co-workers at the University of Groningen have reported in ACIE on a palladium catalzyed anti-Markovnikov oxidation of allylic esters.  This is the opposite of what we see in a Wacker-Tsuji process.

palladium
ACIE paper

Posted in Methodology, Named Reactions, Palladium, Transition Metal, Wacker | Leave a Comment »

Chiral allene synthesis

Posted by naturalproductman on March 20, 2013

Doug Frantz and co-workers at UT San Antonio have reported in JACS on a palladium catalyzed asymmetric approach to synthesizing axially chiral allenes through beta-hydride elimination.

allene

JACS paper

Posted in Allenes, Asymmetric, Methodology, Palladium, Transition Metal | Leave a Comment »

Pd-catalyzed 3 component coupling

Posted by naturalproductman on March 13, 2013

Matthew Sigman and colleague at the University of Utah have reported in JACS on a palladium catalyzed three component coupling reaction.

three

JACS paper

Posted in Cascade Reactions, Methodology, Multi-Component Coupling, Palladium, Transition Metal | Leave a Comment »

Aminopalladation

Posted by naturalproductman on February 26, 2013

Jieping Zhu and co-workers from CNRS have reported in Tetrahedron on an aminopalladation reaction.

aminopalladation

Tetrahedron paper

Posted in Cascade Reactions, Methodology, Palladium, Transition Metal | Leave a Comment »

 
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