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Archive for the ‘Named Reactions’ Category

Kendomycin synthesis

Posted by naturalproductman on March 14, 2014

Hirokazu Arimoto and co-workers from Tohoku University have reported in ACIE on the synthesis of kendomycin.

kendomycin

ACIE paper

Posted in Methodology, Named Reactions, Palladium, Total Synthesis, Transition Metal, Tsuji-Trost | Leave a Comment »

Bischler–Napieralski-Type Cyclization

Posted by naturalproductman on January 13, 2014

Masaya Nakata and co-workers from Keio University have reported in Org Lett on a Bischler-Napieralski type reaction to form isoindolinones.

FC

OL paper

Posted in Bischler-Napieralski reaction, Cascade Reactions, Methodology, Named Reactions | 1 Comment »

Limazepine E synthesis

Posted by naturalproductman on August 30, 2013

Ronalds Zemribo and colleague at the Latvian Institute of Organic Chemistry have reported in Org Lett on a an Ireland-Claisen rearrangement approach to synthesizing limazepine E and barmumycin.

limazepine E

OL paper

Posted in Alkaloids, Cascade Reactions, Ireland-Claisen rearrangement, Methodology, Named Reactions, Pericyclic reactions, Sigmatropic Rearrangements | Leave a Comment »

Aza-Pauson Khand reaction

Posted by naturalproductman on August 30, 2013

Chisato Mukai and co-workers at Kanazawa University have reported in ACIE on an aza-Pauson Khand reaction.

aza

ACIE paper

Posted in Cascade Reactions, Methodology, Named Reactions, Pauson-Khand, Rhodium, Transition Metal | Leave a Comment »

Bolivianine synthesis

Posted by naturalproductman on June 11, 2013

Bo Liu and co-workers at Sichuan University have reported in JACS on a synthesis of bolivianine using a Diels-Alder cascade for the final key step.

JACS paper

Posted in Diels-Alder, Named Reactions, Total Synthesis | Leave a Comment »

Transtaganolide syntheses

Posted by naturalproductman on May 17, 2013

Brian Stoltz and co-workers have reported in ACIE on the syntheses of transtaganolides through an Ireland-Claisen rearrangement/Diels-Alder cascade.

ICR/DA

ACIE paper

Posted in Asymmetric, Cascade Reactions, Claisen rearrangement, Diels-Alder, Methodology, Named Reactions, Sesquiterpenes, Total Synthesis | Leave a Comment »

DYKAT

Posted by naturalproductman on May 9, 2013

Jeffrey Johnson and co-workers at UNC have reported in Org Lett on a dynamic kinetic resolution.

KR

OL paper

Posted in Asymmetric, Friedel-Crafts, Kinetic resolution, Methodology, Named Reactions | Leave a Comment »

Rh-cascade

Posted by naturalproductman on April 22, 2013

Ken Tanaka and co-workers at the Tokyo University of Agriculture and Technology have reported in Org Lett on a rhodium catalyzed cascade reaction to yield substituted cyclopentanones.

rh

OL paper

Posted in Cascade Reactions, Claisen rearrangement, Methodology, Named Reactions, Rhodium, Transition Metal | Leave a Comment »

Anti-Markovnikov oxidation of allylic esters

Posted by naturalproductman on April 18, 2013

Ben Feringa and co-workers at the University of Groningen have reported in ACIE on a palladium catalzyed anti-Markovnikov oxidation of allylic esters.  This is the opposite of what we see in a Wacker-Tsuji process.

palladium
ACIE paper

Posted in Methodology, Named Reactions, Palladium, Transition Metal, Wacker | Leave a Comment »

Towards PF-1018

Posted by naturalproductman on April 2, 2013

Dirk Trauner and co-workers at have reported in Organic Letters on a Stille-Diels Alder cascade approach towards PF-1018.

PF-1018

OL paper

Posted in Cascade Reactions, cross coupling, Diels-Alder, Methodology, Named Reactions, Stille | Leave a Comment »

 
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