Naturalproductman’s Blog

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Archive for the ‘Ferrier’ Category

Ferrier type cascade

Posted by naturalproductman on May 2, 2012

Joseph Kim and co-workers at Sanofi have reported in Tetrahedron Letters on a Ferrier type reaction.

Ferrier

TL paper

Posted in Allenes, Cascade Reactions, Ferrier, Methodology, Named Reactions | Leave a Comment »

Aspergillide synthesis

Posted by naturalproductman on September 28, 2011

Srihari and colleague at IICT have reported in European JOC on the syntheses of aspergillide.

aspergillide

European JOC paper

Posted in Achmatowicz rearrangement, Asymmetric, Ferrier, Macrolides, Methodology, Named Reactions | Leave a Comment »

Tetrodotoxin Synthesis

Posted by naturalproductman on March 25, 2010

Ken-ichi Sato and co-workers from Kanagawa University have recently reported the synthesis of tetrodotoxin in the Bulletin of the Chemical Society of Japan.  There was a key Ferrier rearrangement from a glucose derived intermediate to yield a penta-substituted cyclohexanone.

tetrodotoxin

BCSJ paper

Posted in Cascade Reactions, Ferrier, Methodology, Named Reactions | Leave a Comment »

 
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