Naturalproductman’s Blog

Hey, is that a natural product?!

Archive for the ‘Wacker’ Category

Anti-Markovnikov oxidation of allylic esters

Posted by naturalproductman on April 18, 2013

Ben Feringa and co-workers at the University of Groningen have reported in ACIE on a palladium catalzyed anti-Markovnikov oxidation of allylic esters.  This is the opposite of what we see in a Wacker-Tsuji process.

palladium
ACIE paper

Posted in Methodology, Named Reactions, Palladium, Transition Metal, Wacker | Leave a Comment »

Fusarisetin A synthesis

Posted by naturalproductman on December 30, 2011

Ang Li and co-workers at Shanghai Institute of Organic Chemistry have reported in JACS on the synthesis of fusarisetin A.fusarisetin

 

JACS paper

Posted in Asymmetric, Cascade Reactions, Methodology, Named Reactions, Palladium, Transition Metal, Wacker | Leave a Comment »

Enantioselective Wacker Oxidation

Posted by naturalproductman on June 25, 2010

Hiroaki Sasai and co-workers at Osaka University have published in Org Lett on an enantioselective Wacker cyclization using a palladium catalyst with a SPRIX ligand.

SPRIX

OL paper

Posted in Asymmetric, Cascade Reactions, Methodology, Palladium, Transition Metal, Wacker | Leave a Comment »

 
Follow

Get every new post delivered to your Inbox.

Join 70 other followers