Naturalproductman’s Blog

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Archive for the ‘Wolff rearrangement’ Category

Ketene from a Diazo Compound

Posted by naturalproductman on October 19, 2010

Gunda Georg and co-worker at the University of Minnesota have published in JACS on a silver promoted Wolff rearrangement to access dihydropiperidones via a 6-exo-dig cyclization.

ketene

JACS paper

Posted in Cascade Reactions, Methodology, Ring forming, Silver, Transition Metal, Wolff rearrangement | Leave a Comment »

 
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