Posted by naturalproductman on May 12, 2015
I would call the vinyl halide coupling reaction with an aldehyde using chromium/nickel combination a Nozaki Hiyama Kishi coupling, but maybe because the author is one of the people in the named reaction, it wasn’t mentioned in the paper as the “NHK reaction”, but rather, a Ni/Cr-mediated reaction.
JACS paper 2
Posted in Chromium, cross coupling, Methodology, Named Reactions, Nickel, Polyketides, Total Synthesis | Leave a Comment »
Posted by naturalproductman on April 16, 2015
Alois Furstner and co-workers have reported in ACIE on the synthesis of 5,6-dihydrocineromycin B.
Posted in cross coupling, Macrolides, Named Reactions, Total Synthesis | Leave a Comment »
Posted by naturalproductman on April 12, 2015
Yi-Xia Jia and co-workers have reported in JACS on an intramolecular Heck reaction.
Posted in Cascade Reactions, Heck, Methodology, Named Reactions | Leave a Comment »
Posted by naturalproductman on October 28, 2014
Gregg Keaney and co-workers at H3 Biomedicine have reported in Org Lett on the synthesis of 6-deoxypladienolide D.
Posted in Named Reactions, Polyketides, Suzuki-Miyaura, Total Synthesis | 1 Comment »
Posted by naturalproductman on April 2, 2013
Dirk Trauner and co-workers at have reported in Organic Letters on a Stille-Diels Alder cascade approach towards PF-1018.
Posted in Cascade Reactions, cross coupling, Diels-Alder, Methodology, Named Reactions, Stille | Leave a Comment »