Naturalproductman’s Blog

Hey, is that a natural product?!

Archive for the ‘Transition Metal’ Category

Reactions involving transition metals

C-H activation with Pd

Posted by naturalproductman on March 21, 2015

Erik Alexanian and co-workers have reported in JACS on a palladium catalyzed C-H arylation from alkyl halides.
palladium
JACS paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | 1 Comment »

Bromochlorination of allylic alcohols

Posted by naturalproductman on March 21, 2015

Noah Burns and co-workers at Stanford have reported in JACS on a bromo-chlorination of allylic alcohols.
bromochlorination

JACS paper

Posted in Methodology, Titanium, Transition Metal | Leave a Comment »

Silver mediated (stoichiometric) C-H activation

Posted by naturalproductman on March 5, 2015

Pingping Tang and co-workers from Nankai University have reported in ACIE on a silver mediated trifluoromethylthiolation.

silver

ACIE paper

Posted in C-H activation, Methodology, Silver, Transition Metal | Leave a Comment »

Rh-catalyzed cascade

Posted by naturalproductman on March 5, 2015

P. Andrew Evans and co-workers at Queen’s University have reported in ACIE on a rhodium catalyzed [(3+2)+2] carbocyclization.

rhodium

ACIE paper

Posted in Cascade Reactions, Methodology, Rhodium, Transition Metal | Leave a Comment »

Epoxide and aryl halide coupling

Posted by naturalproductman on March 5, 2015

Daniel Weix and colleague at the University of Rochester have reported in JACS on a coupling between an epoxide and an aryl halide.

epoxide

JACS paper

Posted in Methodology, Nickel, Titanium, Transition Metal | Leave a Comment »

1,1-Arylborylation of terminal alkenes

Posted by naturalproductman on March 5, 2015

Dean Toste and co-workers have reported in JACS on a 1,1-arylborylation of terminal alkenes.

arylborylation

JACS paper

Posted in Cascade Reactions, Methodology, Palladium, Transition Metal | Leave a Comment »

B-H insertions

Posted by naturalproductman on March 5, 2015

Ming-Hua Xu and co-workers from the Chinese Academy of Sciences have reported in JACS on a rhodium catalyzed transformation of a diazo to an organoborane.

B-H

JACS paper

Posted in Carbene, Cascade Reactions, Methodology, Rhodium, Transition Metal | Leave a Comment »

Gold cascade

Posted by naturalproductman on March 5, 2015

Dean Toste and co-workers have reported in JACS on a gold catalyzed Rautenstrauch cascade reaction.

gold

JACS paper

Posted in Cascade Reactions, Gold, Methodology, Named Reactions, Rautenstrauch rearrangement, Transition Metal | Leave a Comment »

Rh-catalyzed arylation

Posted by naturalproductman on March 5, 2015

Tamio Hayashi and colleague at the National University of Singapore have reported in JACS on a rhodium catalyzed asymmetric arylation of an alkenyl sulfone.

rhodium

JACS paper

Posted in Asymmetric, Methodology, Rhodium, Total Synthesis, Transition Metal | Leave a Comment »

Ru-catalyzed hydroacylation

Posted by naturalproductman on March 5, 2015

Vy Dong and co-workers at UC Irvine have reported in JACS on a ruthenium catalyzed hydroacylation that differentiates between an ethyl vs. a methyl substituent on an alkyne.

hydroacylation

JACS paper

Posted in Methodology, Ruthenium, Transition Metal | Leave a Comment »

 
Follow

Get every new post delivered to your Inbox.

Join 77 other followers