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Archive for the ‘Palladium’ Category

C-H activation with Pd

Posted by naturalproductman on March 21, 2015

Erik Alexanian and co-workers have reported in JACS on a palladium catalyzed C-H arylation from alkyl halides.
palladium
JACS paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | 1 Comment »

1,1-Arylborylation of terminal alkenes

Posted by naturalproductman on March 5, 2015

Dean Toste and co-workers have reported in JACS on a 1,1-arylborylation of terminal alkenes.

arylborylation

JACS paper

Posted in Cascade Reactions, Methodology, Palladium, Transition Metal | Leave a Comment »

Alkene methoxycarbonylation

Posted by naturalproductman on February 22, 2015

Matthias Beller and co-workers at Leibniz-Institut für Katalyse an der Universität Rostock have reported in ACIE on a palladium catalyzed methoxycarbonylation of olefins.

Pd

ACIE paper

Posted in Methodology, Palladium, Transition Metal | Leave a Comment »

Alkyl halides from aryl halides

Posted by naturalproductman on November 8, 2014

Zhenfeng Xi and co-workers from SIOC have reported in ACIE on the transfer of a halogen from an aryl group to an alkyl group.

reductive elimination

ACIE paper

Posted in Mechanistic, Methodology, Palladium, Transition Metal | Leave a Comment »

Pd pi-allyl

Posted by naturalproductman on November 8, 2014

Shu-Li You and co-workers at SIOC have reported in JACS on some mechanistic studies of a Pd pi-allyl chemistry.

pi allyl

JACS paper

Posted in Asymmetric, Mechanistic, Methodology, Named Reactions, Palladium, Transition Metal, Tsuji-Trost | Leave a Comment »

Asymmetric aza-Pinacol rearrangement

Posted by naturalproductman on November 4, 2014

Yong-Gui Zhou and co-workers at SIOC have reported in JACS on an asymmetric aza-Pinacol rearrangement.

asymmetric

JACS paper

Posted in Asymmetric, Aza-Pinacol, Cascade Reactions, Methodology, Named Reactions, Palladium, Ring expansion, Transition Metal | Leave a Comment »

Palladium catalyzed decarboxylative cycloaddition

Posted by naturalproductman on August 30, 2014

Yong Jian Zhang and co-workers at Shanghai Jiao Tong University have reported in ACIE on a palladium catalyzed decarboxylative cycloaddition.

palladium

ACIE paper

Posted in Cascade Reactions, Cycloaddition, Methodology, Palladium, Transition Metal | 1 Comment »

Palladium catalyzed decarboxylative cycloaddition

Posted by naturalproductman on August 30, 2014

Yong Jian Zhang and co-workers at Shanghai Jiao Tong University have reported in ACIE on a palladium catalyzed decarboxylative cycloaddition.

palladium

ACIE paper

Posted in Cascade Reactions, Cycloaddition, Methodology, Palladium, Transition Metal | Leave a Comment »

Pd-catalyzed C-N bond formation

Posted by naturalproductman on June 5, 2014

Matthew Gaunt and co-workers from the University of Cambridge have reported in Nature on a palladium catalyzed intramolecular C-N bond formation from C-H bonds. I am reminded of the ACIE paper from Frances Arnold’s group at Caltech where they used a P450 mutant to do a similar reaction.

 

Nature paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | Leave a Comment »

Macrolactonization towards neopeltolide

Posted by naturalproductman on May 13, 2014

Mingji Dai and co-workers from Purdue have reported in ACIE on alkoxycarbonylative macrocyclization.

Pd

ACIE paper

Posted in Macrolides, Methodology, Palladium, Transition Metal | Leave a Comment »

 
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