Naturalproductman’s Blog

Hey, is that a natural product?!

Archive for the ‘Palladium’ Category

Pd-catalyzed DKR

Posted by naturalproductman on April 16, 2015

Xinjun Luan and co-workers have reported in JACS on a palladium catalyzed dynamic kinetic resolution of biaryls to spirocyclic centers.

spirocycle

JACS paper

Posted in Cascade Reactions, Kinetic resolution, Methodology, Palladium, Transition Metal | Leave a Comment »

C-H Activation Cascade

Posted by naturalproductman on April 16, 2015

Kevin Booker Millburn and colleague at the University of Bristol have reported in ACIE on a palladium C-H activation cascade reaction.

C-H
ACIE paper

Posted in C-H activation, Cascade Reactions, Methodology, Palladium, Transition Metal | Leave a Comment »

Alkyne + Formic Acid = Vinyl carboxylic acid

Posted by naturalproductman on April 12, 2015

Qi-Lin Zhou and co-workers from Nankai University have reported in ACIE on a palladium catalyzed hydrocarboxylation of alkynes.

Pd

ACIE paper

Posted in Methodology, Palladium, Transition Metal | Leave a Comment »

Arylsilane for C-H activation

Posted by naturalproductman on April 12, 2015

Jin-Quan Yu and co-workers have reported in JACS on a cross coupling reaction between an aryl silane and a C-H bond.

C-H

JACS paper

Posted in C-H activation, cross coupling, Methodology, Palladium, Transition Metal | Leave a Comment »

C-H activation with Pd

Posted by naturalproductman on March 21, 2015

Erik Alexanian and co-workers have reported in JACS on a palladium catalyzed C-H arylation from alkyl halides.
palladium
JACS paper

Posted in C-H activation, Methodology, Palladium, Transition Metal | 1 Comment »

1,1-Arylborylation of terminal alkenes

Posted by naturalproductman on March 5, 2015

Dean Toste and co-workers have reported in JACS on a 1,1-arylborylation of terminal alkenes.

arylborylation

JACS paper

Posted in Cascade Reactions, Methodology, Palladium, Transition Metal | Leave a Comment »

Alkene methoxycarbonylation

Posted by naturalproductman on February 22, 2015

Matthias Beller and co-workers at Leibniz-Institut für Katalyse an der Universität Rostock have reported in ACIE on a palladium catalyzed methoxycarbonylation of olefins.

Pd

ACIE paper

Posted in Methodology, Palladium, Transition Metal | Leave a Comment »

Alkyl halides from aryl halides

Posted by naturalproductman on November 8, 2014

Zhenfeng Xi and co-workers from SIOC have reported in ACIE on the transfer of a halogen from an aryl group to an alkyl group.

reductive elimination

ACIE paper

Posted in Mechanistic, Methodology, Palladium, Transition Metal | Leave a Comment »

Pd pi-allyl

Posted by naturalproductman on November 8, 2014

Shu-Li You and co-workers at SIOC have reported in JACS on some mechanistic studies of a Pd pi-allyl chemistry.

pi allyl

JACS paper

Posted in Asymmetric, Mechanistic, Methodology, Named Reactions, Palladium, Transition Metal, Tsuji-Trost | Leave a Comment »

Asymmetric aza-Pinacol rearrangement

Posted by naturalproductman on November 4, 2014

Yong-Gui Zhou and co-workers at SIOC have reported in JACS on an asymmetric aza-Pinacol rearrangement.

asymmetric

JACS paper

Posted in Asymmetric, Aza-Pinacol, Cascade Reactions, Methodology, Named Reactions, Palladium, Ring expansion, Transition Metal | Leave a Comment »

 
Follow

Get every new post delivered to your Inbox.

Join 78 other followers