Naturalproductman’s Blog

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Archive for the ‘Wagner-Meerwein rearrangement’ Category

Trigonoliimine C synthesis

Posted by naturalproductman on July 3, 2011

Uttam Tambar and co-workers at UT Southwestern have reported in JACS on their racemic synthesis of trigonoliimine C.

trigonoliimine C

JACS paper

Posted in Alkaloids, Cascade Reactions, Dimer, Hypervalent Iodine, Indoles, Methodology, Named Reactions, Wagner-Meerwein rearrangement | Leave a Comment »

Oxidative Methyl Migration by a P450

Posted by naturalproductman on February 4, 2011

David Crane and co-workers at Brown University have reported in JACS on a cytochrome P450 enzyme that is responsible for an oxidative rearrangement of a methyl group.

p450

JACS paper

Posted in Enzymatic, Methodology, Named Reactions, Sesquiterpenoids, Wagner-Meerwein rearrangement | Leave a Comment »