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Archive for the ‘Platinum’ Category

Asymmetric [3+2] with Platinum

Posted by naturalproductman on June 14, 2010

Nobuharu Iwasawa and co-workers at the Tokyo Institute of Technology have published in JACS on a platinum catalyzed [3+2] cycloaddition reaction between an alkynyl ketone and enol.

3+2

JACS paper

Posted in Asymmetric, Cascade Reactions, Cycloaddition, Methodology, Pericyclic reactions, Platinum, Transition Metal | Leave a Comment »

Pt-Cyclization

Posted by naturalproductman on June 2, 2010

Rai-Shung Liu and co-workers at National Tsing-Hua University have published in Chemical Communications on a Pt-catalyzed cyclization of an enyne via a 6-endo-dig cyclization.

cyclopropane

Chem Comm paper

Posted in C-H activation, Cascade Reactions, Methodology, Platinum, Transition Metal | Leave a Comment »

Platinum Containing Pyrylium Cycloadditions

Posted by naturalproductman on April 16, 2010

Chang Ho Oh and co-workers at Hanyang University have recently reported in Chemical Communications on generation of pyrylium ions from an aldehyde containing an alkyne in the presence of platinum.  These ylides that are formed may undergo cyclizations with alkenes to form polycyclic compounds from linear starting materials.

ylide

Chem Comm paper

Posted in Cascade Reactions, Cycloaddition, Methodology, Platinum, Transition Metal, Ylides | Leave a Comment »

Propargylamide Cascade

Posted by naturalproductman on April 11, 2010

Matthias Beller and co-workers from the Universitat Rostock have recently published in Tetrahedron on a cascade cyclization using a propargyl amide.

cascade

Tetrahedron paper

Posted in Cascade Reactions, Copper, cross coupling, Gold, Methodology, Palladium, Platinum, Ring forming, Transition Metal | Leave a Comment »

Platinum Cascade Cyclization

Posted by naturalproductman on February 26, 2010

Chang Ho Oh and Hanyang University have recently published in Organic Letters  on a platinum catalyzed cyclization process of an enynylbenzaldehyde.

enynyl benzaldehyde

OL paper

Posted in Methodology, Platinum, Transition Metal | Leave a Comment »

Pt-Catalyzed Cascade

Posted by naturalproductman on January 25, 2010

Xuegong She and co-workers have recently published in JACS on a Pt-catalyzed cascade reaction that involves a propargyl acetate tethered with a terminal alkene.

cascade

JACS paper

Posted in Cascade Reactions, Methodology, Platinum, Transition Metal | Leave a Comment »