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Alkyne to caged compound

Posted by naturalproductman on June 9, 2011

Qi-Dong You and co-workers from China Pharmaceutical University have reported in Tetrahedron on a diyne compound undergoing a hydrogenation/Claisen/Diels-Alder cascade to afford the caged carbon skeleton of gaudichaudione A and isomorellin.

palladium

Tetrahedron paper

This entry was posted on June 9, 2011 at 9:45 pm and is filed under Cascade Reactions, Claisen rearrangement, Diels-Alder, Methodology, Named Reactions, Palladium, Transition Metal. You can follow any responses to this entry through the RSS 2.0 feed. You can leave a response, or trackback from your own site.

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Alkyne to caged compound

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