Naturalproductman’s Blog

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Cation-pi cyclization with platinum

Posted by naturalproductman on May 13, 2011

Michel Gagne and co-workers at UNC have reported in ACIEE on their platinum mediated cation-pi cyclization – this paper isolates the platinum complexed to the cyclized product.  This reaction is very popular – as we know from Johnson’s observations.

platinum

ACIEE paper

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